甲酰化酞菁铜的制备及应用研究+文献综述
关键词： 酞菁铜；取代酞菁；文尔斯迈尔反应；偶氮颜料；吲哚啉
The preparation and application of substituted Phthalocyanine
Abstract: This study is for the company’s existing copper phthalocyanine (A) and n-hydroxy-methyl phenyl azo naphthalene-carboxamide (B) development of applied research projects. A and B are produced by two commercial products, A is a blue pigment,B is a red pigment.They are not only organic solvent resistance, acid and alkali, excellent corrosion resistance and light resistance, weather resistance, temperature resistance is also very good, already widely used in paints, plastics, inks and other industries; Indole carbon-Ching has large molar extinction coefficient, good, light and fluorescence properties and high thermal stability, will replace the indole into the molecular structure of A and B, can get the application prospect of new paint. After Vilsmeier reaction to a raw materials, preparation of acid copper phthalocyanine(C); With trimethyl-substituted indoline as raw material, and iodide salts get indoline salts (D), D condensation reactions with the B and C are respectively 1-ethyl- -3,3-dimethyl-2-(β-n-phenyl-2-hydroxy-4-of for mamide styryl-azo naphthalene)-3H-indole iodide(E) and 1-ethyl-3,3-dimethyl -2-(β-phthalocyanine copper vinyl) -3H-indole iodide (F). Focused its investigation on compound preparation of C and B, C with active methylene compounds indoline D feasibility. Experimental results show that: Phthalocyanine through Vilsmeier reaction of Carbonyl get compound C, Through a condensation reaction of aromatic aldehyde with active methylene compounds are chemical compounds E, Compound F preparation is difficult to achieve under the existing conditions.
Keywords: Copper Phthalocyanine; Substituted phthalocyanine; Vilsmeier reaction; Azo pigments; Indoline
目录
1 前言 1
1.1 有机颜料及荧光颜料 1
1.1.1 有机颜料的概述及分类 1
1.1.2 有机颜料的改性 1
1.1.3 荧光颜料的概述 2
1.1.4 有机荧光颜料的化学组成 2
1.2 酞菁及取代酞菁概述 3
1.2.1 酞菁发展概况 3
1.2.2 酞菁及酞菁铜的结构 3
1.2.3 酞菁及酞菁铜的性质及应用 4
1.2.4 取代酞菁的性质及应用 4
1.2.5 酞菁铜的制备 5